{ "id": "epvj3cyrh5", "slug": "molybdenum-ditelluride", "title": "Molybdenum ditelluride", "updated": "2026-10-15", "topic_path": [ { "id": "physical", "label": "Physical world and mathematics", "api_url": "https://www.edgepedia.org/api/v1/topics/physical" }, { "id": "physical.physics", "label": "Physics", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics" }, { "id": "physical.physics.matter-and-radiation", "label": "Matter and radiation physics", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics.matter-and-radiation" }, { "id": "physical.physics.matter-and-radiation.condensed-matter", "label": "Condensed matter physics", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics.matter-and-radiation.condensed-matter" }, { "id": "physical.physics.matter-and-radiation.condensed-matter.cm-electronic", "label": "Electronic and magnetic properties", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics.matter-and-radiation.condensed-matter.cm-electronic" }, { "id": "physical.physics.matter-and-radiation.condensed-matter.cm-band-theory", "label": "Band theory and electron transport", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics.matter-and-radiation.condensed-matter.cm-band-theory" }, { "id": "physical.physics.matter-and-radiation.condensed-matter.cm-band-theory.dirac-and-topological-bands", "label": "Graphene, Dirac materials, and topological bands", "api_url": "https://www.edgepedia.org/api/v1/topics/physical.physics.matter-and-radiation.condensed-matter.cm-band-theory.dirac-and-topological-bands" } ], "geo": [ { "id": "geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-band-theory", "label": "Western Europe · 2001 to 2020: Band theory and electron transport", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-band-theory", "path": [ { "id": "geo.weu", "label": "Western Europe", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu" }, { "id": "geo.weu.t2001", "label": "Western Europe · 2001 to 2020", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001" }, { "id": "geo.weu.t2001.physical", "label": "Physical world and mathematics", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical" }, { "id": "geo.weu.t2001.physical.physics", "label": "Physics", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics" }, { "id": "geo.weu.t2001.physical.physics.matter-and-radiation", "label": "Matter and radiation physics", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics.matter-and-radiation" }, { "id": "geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter", "label": "Condensed matter physics", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter" }, { "id": "geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-electronic", "label": "Electronic and magnetic properties", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-electronic" }, { "id": "geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-band-theory", "label": "Band theory and electron transport", "api_url": "https://www.edgepedia.org/api/v1/geo/geo.weu.t2001.physical.physics.matter-and-radiation.condensed-matter.cm-band-theory" } ] } ], "excerpt": "Molybdenum ditelluride (MoTe₂) is a layered transition metal dichalcogenide, about 0.7 nm per layer, whose three crystal phases span semiconductor, metal, and type-II Weyl semimetal behavior.", "snippet": "Molybdenum ditelluride (MoTe₂) is a layered transition metal dichalcogenide, about 0.7 nm per layer, whose three crystal phases span semiconductor, metal, and type-II Weyl semimetal behavior.", "node": "physical.physics.matter-and-radiation.condensed-matter.cm-band-theory.dirac-and-topological-bands", "markdown": "# Molybdenum ditelluride\n\n**Molybdenum ditelluride** (MoTe₂) is a layered transition metal dichalcogenide in which each molybdenum atom is sandwiched between two tellurium atoms, with individual layers about 0.7 nm thick stacked by weak van der Waals forces[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236) • [2](https://doi.org/10.1088/1361-6463/AD7FF8). It is a polymorphic material: near room temperature it can exist in three crystal phases, the hexagonal 2H (α) phase, the monoclinic 1T′ (β) phase, and the orthorhombic T_d (γ) phase, which differ in lattice structure, band structure, and optical fingerprints[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236) • [3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/). This proximity of phases with very different electronic behavior, from semiconductor to metal to type-II Weyl semimetal, is the basis of most research interest in the compound[4](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/).\n\n| Key fact | Detail |\n|---|---|\n| Crystal phases | Three phases: 2H (hexagonal, P6₃/mmc), 1T′ (monoclinic, P2₁/m), and T_d (orthorhombic, Pmn2₁); bulk crystals convert from 1T′ to T_d below about 250 K, while flakes thinner than about 12 nm stay orthorhombic up to and beyond room temperature[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236) |\n| Layer thickness | Each Te–Mo–Te layer is 0.7 nm thick; layers are bonded by weak van der Waals forces[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236) • [2](https://doi.org/10.1088/1361-6463/AD7FF8) |\n| Electronic character | 2H is a semiconductor (≈1.1 eV bandgap); 1T′ is metallic; T_d is a type-II Weyl semimetal with Weyl nodes near the Fermi level[4](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/) |\n| Bandgap of 2H | 0.8 eV indirect in bulk and few-layer form, becoming a 1.1 eV direct gap in monolayers[3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/) |\n| Phase-transition energy | The 2H and 1T′ phases differ by only 35 meV; the transition costs <50 meV because the Mo–Te electronegativity difference is only about 0.3[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236) |\n| Structural transition temperature | Bulk crystals convert from monoclinic to orthorhombic below about 250 K; flakes thinner than about 12 nm stay orthorhombic up to and beyond room temperature[5](https://doi.org/10.1103/PhysRevB.97.041410) |\n| Superconductivity | The T_d Weyl semimetal phase becomes superconducting at very low temperature, with a T_c of 0.10 K[2](https://doi.org/10.1088/1361-6463/AD7FF8) |\n\n## Crystal phases\n\nIn the 2H phase, hexagonal sheets of molybdenum atoms lie between two hexagonal planes of tellurium atoms in a trigonal prismatic arrangement, giving a honeycomb-like in-plane structure[2](https://doi.org/10.1088/1361-6463/AD7FF8) • [1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236). The 1T′ phase has a distorted centered honeycomb in-plane structure with a slightly inclined interplane arrangement and a monoclinic β angle of 93°55′; the T_d phase is structurally similar but more regular, with a β angle of 90°[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236). In monolayer form the 1T′ and T_d arrangements are essentially identical and difficult to distinguish; the phases are primarily recognized in side view, which is possible in few-layer crystals[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236).\n\n**Phase proximity.** The energy difference between the 2H and 1T′ phases is only 35 meV, and the transition between them costs less than 50 meV, a consequence of the small electronegativity difference of about 0.3 between Mo and Te atoms[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236). Because of this small barrier, 2H-MoTe₂ converts to the 1T′ phase under excess tellurium deficiency or strain[3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/). Calculations indicate that biaxial or uniaxial tensile strain can drive the transition: at 10% biaxial tensile strain the 1T′ phase becomes more stable than 2H, with an energy barrier of 0.90 eV per formula unit between the phases[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236). Phase engineering of telluride TMDs is generally easier than for their sulfide counterparts for the same reason, the much smaller energy difference between the 2H and 1T′ structures[4](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/).\n\n## Electronic properties\n\nThe three phases span three distinct electronic regimes. 2H-MoTe₂ is a semiconductor with a bandgap of about 1.1 eV; in bulk and few-layer form the gap is indirect at 0.8 eV, and thinning to a monolayer converts it to a direct gap of 1.1 eV[4](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/) • [3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/). The 1T′ phase presents a metallic ground state, although some reports designate few-layer 1T′-MoTe₂ as a semiconductor[4](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/) • [3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/). Few-layer 1T′-MoTe₂ also shows a bandgap opening of up to 60 meV due to strong interband spin-orbit coupling[1](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236).\n\nThe 1T′ phase leads to strong anisotropic behavior, including strong anisotropic absorption in which polarized optical images disappear when rotated through 90°[2](https://doi.org/10.1088/1361-6463/AD7FF8).\n\n## Weyl semimetal physics\n\nThe low-temperature orthorhombic T_d phase is a candidate type-II Weyl semimetal, a topological metal in which Weyl points sit at the touching points of electron and hole pockets tilted in the same direction[6](https://www.nature.com/articles/nmat4685). [Ab initio](https://www.edgepedia.org/ab-initio) calculations based on an x-ray diffraction structure determined at 100 K found four type-II Weyl points between consecutive bands, and predicted a series of strain-driven topological phase transitions[7](https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.117.056805). Compared with its cousin WTe₂, the spacing between each pair of Weyl points in MoTe₂ is large, about 4 percent of the reciprocal lattice, six times larger than in WTe₂[8](https://arxiv.org/abs/1508.03501).\n\n**Experimental evidence.** [Angle-resolved photoemission spectroscopy](https://www.edgepedia.org/angle-resolved-photoemission-spectroscopy) (ARPES) experiments reported the discovery of a type-II Weyl semimetal state in pure MoTe₂, with two sets of Weyl points located at different binding energies above the [Fermi level](https://www.edgepedia.org/fermi-level)[6](https://www.nature.com/articles/nmat4685). Kaminski and colleagues identified [Fermi arcs](https://www.edgepedia.org/fermi-arcs) (surface electronic states linking Weyl points), Weyl points, and novel surface states in bulk T_d-MoTe₂ by ARPES, providing experimental evidence for T_d-MoTe₂ as a type-II Weyl semimetal[3](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/). Laser-ARPES work on polar 1T′-MoTe₂ found that the Fermi arc connects the identical pair of Weyl nodes on one side of the polar crystal surface but connects different pairs of Weyl nodes on the other side[9](https://arxiv.org/abs/1611.02168).\n\n**Interpretation debates.** The topological interpretation has been contested in detail. One ARPES study reported a surface state arc dispersing between the valence and conduction bands even in the topologically trivial phase, concluding that a surface [Fermi arc](https://www.edgepedia.org/fermi-arc) is not an unambiguous fingerprint of a topologically nontrivial phase[10](https://doi.org/10.1103/PhysRevB.95.041408). Later theoretical work argued that the huge arc-like surface states seen by ARPES and scanning tunneling microscopy in MoTe₂ and WTe₂ are not the much smaller topological Fermi arcs of the bulk Weyl points[11](https://arxiv.org/abs/1806.11116).\n\n## Dimensionality and the room-temperature orthorhombic phase\n\nBulk crystals undergo a structural phase transition from the monoclinic β phase to the inversion-symmetry-breaking orthorhombic T_d phase at about 250 K[5](https://doi.org/10.1103/PhysRevB.97.041410) • [12](https://journals.aps.org/prx/abstract/10.1103/PhysRevX.6.031021). [Raman spectroscopy](https://www.edgepedia.org/raman-spectroscopy) and transport measurements on thin flakes protected from oxidation found that in samples below about 12 nm a single orthorhombic phase persists up to and beyond room temperature, attributed to c-axis confinement lowering the energy of an out-of-plane hole band and stabilizing the orthorhombic structure[5](https://doi.org/10.1103/PhysRevB.97.041410). This result suggests that Weyl nodes, which require inversion symmetry breaking, may be observable in thin MoTe₂ at room temperature rather than only at cryogenic temperatures[5](https://doi.org/10.1103/PhysRevB.97.041410).\n\n## Superconductivity and related compounds\n\nThe T_d Weyl semimetal phase behaves as a superconductor at very low temperatures, with a critical temperature of 0.10 K[2](https://doi.org/10.1088/1361-6463/AD7FF8). The orthorhombic phase was discovered to be superconducting in the same experimental work that first proposed it as a Weyl semimetal candidate[8](https://arxiv.org/abs/1508.03501). MoTe₂ belongs to the broader family of transition metal di-tellurides, whose polytypes, phase transitions, and topological, thermoelectric, and magnetic properties have made them a focus of electronics research[13](https://www.sciencedirect.com/science/article/pii/S1369800124009910).\n\n## References\n\n1. [Advances in two-dimensional molybdenum ditelluride (MoTe₂): A comprehensive review of properties, preparation methods, and applications, SusMat (2024)](https://onlinelibrary.wiley.com/doi/full/10.1002/sus2.236)\n2. [Multifunctional 2D MoTe₂: Recent developments and future perspectives, Journal of Physics D](https://doi.org/10.1088/1361-6463/AD7FF8)\n3. [Recent Progress in Two-Dimensional MoTe₂ Hetero-Phase Homojunctions, PMC](https://pmc.ncbi.nlm.nih.gov/articles/PMC8746702/)\n4. [Chemical Vapor Deposition Mediated Phase Engineering for 2D Transition Metal Dichalcogenides, PMC](https://pmc.ncbi.nlm.nih.gov/articles/PMC11935802/)\n5. [Dimensionality-driven orthorhombic MoTe₂ at room temperature, Physical Review B 97, 041410(R) (2018)](https://doi.org/10.1103/PhysRevB.97.041410)\n6. [Spectroscopic evidence for a type II Weyl semimetallic state in MoTe₂, Nature Materials](https://www.nature.com/articles/nmat4685)\n7. [MoTe₂: A Type-II Weyl Topological Metal, Physical Review Letters 117, 056805](https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.117.056805)\n8. [Prediction of the Weyl semimetal in the orthorhombic MoTe₂, arXiv](https://arxiv.org/abs/1508.03501)\n9. [Observation of spin-polarized bands and domain-dependent Fermi arcs in polar Weyl semimetal MoTe₂, arXiv](https://arxiv.org/abs/1611.02168)\n10. [Persistence of a surface state arc in the topologically trivial phase of MoTe₂, Physical Review B 95, 041408](https://doi.org/10.1103/PhysRevB.95.041408)\n11. [Higher-Order Topology, Monopole Nodal Lines, and the Origin of Large Fermi Arcs in XTe₂ (X=Mo,W), arXiv](https://arxiv.org/abs/1806.11116)\n12. [Fermi Arcs and Their Topological Character in the Candidate Type-II Weyl Semimetal MoTe₂, Physical Review X 6, 031021](https://journals.aps.org/prx/abstract/10.1103/PhysRevX.6.031021)\n13. [Reviewing two-dimensional transition metal di-tellurides (TMDTs), Materials Science in Semiconductor Processing (2025)](https://www.sciencedirect.com/science/article/pii/S1369800124009910)\n\n---\n*Topic: Encyclopedia › Physical world and mathematics › Physics › Matter and radiation physics › Condensed matter physics › Electronic and magnetic properties › Band theory and electron transport › Graphene, Dirac materials, and topological bands*\n\n*Initially written Oct 15, 2026*\n\n*Copyright 2026 EdgeChat AI, a subsidiary of Biostate AI.*\n\nLicense: Edgepedia Community License 1.0, https://www.edgepedia.org/edgepedia/license\n", "same_as": [], "url": "https://www.edgepedia.org/molybdenum-ditelluride", "markdown_url": "https://www.edgepedia.org/molybdenum-ditelluride.md", "license": { "name": "Edgepedia Community License 1.0", "url": "https://www.edgepedia.org/edgepedia/license", "summary": "Free with credit, commercial use included. AI training is open to everyone. For other uses, organizations over USD 100M in revenue or 100M monthly users license separately.", "spdx": "LicenseRef-Edgepedia-Community-1.0" }, "credit": "\"Molybdenum ditelluride\", Edgepedia (EdgeChat), https://www.edgepedia.org/molybdenum-ditelluride. Edgepedia Community License 1.0.", "credit_md": "\"[Molybdenum ditelluride](https://www.edgepedia.org/molybdenum-ditelluride)\", Edgepedia (EdgeChat), [https://www.edgepedia.org/molybdenum-ditelluride](https://www.edgepedia.org/molybdenum-ditelluride). [Edgepedia Community License 1.0](https://www.edgepedia.org/edgepedia/license).", "credit_html": "\"Molybdenum ditelluride\", Edgepedia (EdgeChat), https://www.edgepedia.org/molybdenum-ditelluride. Edgepedia Community License 1.0.", "speakable": "Molybdenum ditelluride is a layered transition metal dichalcogenide, about 0.7 nm per layer, whose three crystal phases span semiconductor, metal, and type-II Weyl semimetal behavior." }