# Coercivity

**Coercivity** is the intensity of the external magnetic field required to reduce the magnetization of a ferromagnetic material to zero after the material has been magnetized to saturation. It is denoted H<sub>c</sub>, called the coercive field or (in older literature) the coercive force, and is measured in amperes per meter (A/m) or oersteds (Oe).<sup>[1](https://archive.nptel.ac.in/content/storage2/courses/115103038/pdf/mod5.pdf)</sup><sup> • </sup><sup>[2](https://technav.ieee.org/topic/coercive-force/)</sup> Coercivity measures a material's resistance to demagnetization and is one of the central parameters of the magnetic hysteresis loop, the curve traced as magnetization responds to a field cycled between positive and negative values.<sup>[1](https://archive.nptel.ac.in/content/storage2/courses/115103038/pdf/mod5.pdf)</sup><sup> • </sup><sup>[3](https://openstax.org/books/university-physics-volume-2/pages/12-7-magnetism-in-matter)</sup>

| Key fact | Detail |
|---|---|
| Definition | Reverse field that brings magnetization (or induction) to zero after saturation; symbol H<sub>c</sub>, units A/m or Oe<sup>[1](https://archive.nptel.ac.in/content/storage2/courses/115103038/pdf/mod5.pdf)</sup> |
| Soft vs hard | Soft magnetic materials: H<sub>c</sub> below about 10<sup>3</sup> A/m; hard (permanent magnet) materials: above 10<sup>4</sup> A/m<sup>[4](https://www.sciencedirect.com/topics/chemistry/magnetic-material)</sup> |
| Extrinsic property | Coercivity depends on microstructure (grain size, defects, grain boundaries) as well as intrinsic anisotropy<sup>[5](https://www.sciencedirect.com/topics/engineering/coercivity)</sup> |
| Working formula | H<sub>c</sub>(T) = αH<sub>A</sub>(T) − N<sub>eff</sub>M<sub>s</sub>(T), combining defect/misalignment effects and the demagnetizing field<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup> |
| Grain-size effect | In Nd-Fe-B magnets coercivity rises as grain size falls, originally fitted as H<sub>c</sub> = a − b lnD<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup> |
| Measurement standards | IEC 60404-7 covers open-circuit measurement from 0.2 A/m to 160 kA/m; ASTM A977 covers hysteresigraph testing of high-coercivity magnets<sup>[7](https://www.evs.ee/en/evs-en-iec-60404-7-2020)</sup><sup> • </sup><sup>[8](https://store.astm.org/a0977_a0977m-07.html)</sup> |
| Typical spread | Supermalloy H<sub>c</sub> ≈ 0.004 gauss versus Alnico V ≈ 550 gauss<sup>[9](https://www.feynmanlectures.caltech.edu/II_37.html)</sup> |

## Position on the hysteresis loop

When a ferromagnet is driven to saturation and the applied field is then reversed, magnetization does not return to zero when the field does; the material retains remanence. The reverse field at which the magnetization first reaches zero is the coercivity. On the induction (B-H) loop, the corresponding intercept is the coercive field in the induction sense, and the two definitions are often used interchangeably, though they are distinct quantities.<sup>[1](https://archive.nptel.ac.in/content/storage2/courses/115103038/pdf/mod5.pdf)</sup><sup> • </sup><sup>[10](https://www2.fisica.unlp.edu.ar/magnet/Cullity_Graham.pdf)</sup>

**Two coercivities for magnets.** Permanent-magnet practice distinguishes bH<sub>c</sub>, the reverse field at which the magnetic induction B becomes zero, from jH<sub>c</sub> (also written H<sub>ci</sub>), the intrinsic coercivity at which the vector sum of the micro magnetic dipole moments is zero.

## Soft and hard magnetic materials

The coercivity value sorts ferromagnetic materials into two engineering classes. Soft magnetic materials, with H<sub>c</sub> below about 10<sup>3</sup> A/m (often well below 100 A/m), follow an applied field closely and lose little energy per cycle; they serve as cores in transformers, inductors, motors, and sensors. Hard magnetic materials, with H<sub>c</sub> above 10<sup>4</sup> A/m, retain strong remanence and are used as permanent magnets.<sup>[4](https://www.sciencedirect.com/topics/chemistry/magnetic-material)</sup><sup> • </sup><sup>[11](https://technav.ieee.org/topic/soft-magnetic-materials/)</sup> Because coercivity directly controls hysteresis loss per cycle, minimizing it is a design goal for soft materials, while a high remanence combined with high coercivity is essential for permanent magnets.<sup>[11](https://technav.ieee.org/topic/soft-magnetic-materials/)</sup><sup> • </sup><sup>[12](https://files.core.ac.uk/download/pdf/62733797.pdf)</sup>

The spread is wide. In Richard Feynman's tabulation, supermalloy has a coercive force of about 0.004 gauss while transformer silicon steel is about 0.05 gauss, armco iron about 0.6 gauss, and Alnico V about 550 gauss.<sup>[9](https://www.feynmanlectures.caltech.edu/II_37.html)</sup>

## Physical origin

Coercivity is an extrinsic property: it depends not only on intrinsic magnetic parameters such as the anisotropy field H<sub>A</sub> and saturation magnetization M<sub>s</sub>, but on the microstructure.<sup>[5](https://www.sciencedirect.com/topics/engineering/coercivity)</sup> In a polycrystalline material, domain walls moving under an applied field become pinned at strains, dislocations, impurities, and grain boundaries; the wall sticks until the field rises enough for it to snap past, and this jerky motion (the [Barkhausen effect](https://www.edgepedia.org/barkhausen-effect)) is the microscopic basis of hysteresis and its energy loss.<sup>[9](https://www.feynmanlectures.caltech.edu/II_37.html)</sup> Local variations in magnetic properties produce local variations in domain-wall energy and thereby forces that resist wall motion.<sup>[5](https://www.sciencedirect.com/topics/engineering/coercivity)</sup>

A common working expression for permanent magnets is

\[ H_{c}(T) = \alpha H_{A}(T) - N_{\mathrm{eff}} M_{s}(T) \]

where the first term captures the reduction of the anisotropy field by defects and grain misalignment (parameter α) and the second term the reduction due to the [demagnetizing field](https://www.edgepedia.org/demagnetizing-field), with N<sub>eff</sub> an effective demagnetizing factor.<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup> The relevant length scale is the domain-wall thickness, around 4 nm in rare-earth magnets.<sup>[13](https://doi.org/10.1088/2043-6254/aa597c)</sup>

## Coercivity in Nd-Fe-B magnets

Sintered Nd-Fe-B magnets, the dominant high-performance permanent magnets, illustrate how microstructure engineering controls coercivity. Their average grain size is above 3 μm, and the accepted reversal mechanism is nucleation of demagnetized domains at edge defects and sharp corners of Nd<sub>2</sub>Fe<sub>14</sub>B grains with low anisotropy constant K; as a result the achieved coercivity is far below the anisotropy field H<sub>A</sub> of the 2:14:1 phase, roughly 0.2 H<sub>A</sub>, because of intergranular exchange coupling through a ferromagnetic intergranular phase.<sup>[5](https://www.sciencedirect.com/topics/engineering/coercivity)</sup><sup> • </sup><sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup>

**Grain size.** Coercivity of anisotropic Nd-Fe-B increases as grain size decreases, originally described by the linear-in-log relation H<sub>c</sub> = a − b lnD of Ramesh et al. Micromagnetic simulations attribute the gain to a lower effective demagnetizing constant N<sub>eff</sub> and reduced stray field from neighboring grains as grains shrink; the effective demagnetizing field N<sub>eff</sub>M<sub>s</sub> falls with grain size, raising coercivity.<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup> Below about 3 μm, conventional powder processing can instead reduce coercivity, because oxidation of metallic Nd during sintering leaves the grains without the Nd-rich intergranular phase needed for magnetic isolation.<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup>

**Grain boundary diffusion.** Coating sintered magnets with Dy or Tb (as oxides, fluorides, or pure metals) and heat treating at 800–1000 °C for 3–10 h diffuses the heavy rare earth into the magnet and forms an HRE-enriched shell around each Nd<sub>2</sub>Fe<sub>14</sub>B grain with a high anisotropy field. Because only a small amount of the heavy rare earth is used locally, the remanence loss from antiferromagnetic Dy-Fe coupling is minimized. This process is now widely used to make high-coercivity magnets for traction motors and wind turbines.<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup>

**Temperature.** Coercivity of Nd-Fe-B falls severely at elevated temperature. Its thermal stability is quantified by the temperature coefficient β<sub>Hc</sub> = ΔH<sub>c</sub> / (H<sub>c</sub>(RT)·ΔT); a typical value for a Dy-free sintered magnet is about −0.6% K<sup>−1</sup> at 160 °C.<sup>[6](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)</sup>

## Measurement

Coercivity is measured by tracing the hysteresis loop. For soft materials, ring samples or frames made entirely of the test material close the flux path; such methods do not apply to permanent magnets, which are instead incorporated in a magnetic circuit with a closed flux path on a hysteresigraph. ASTM A977/A977M covers determination of initial magnetization, demagnetization, and recoil curves of hard materials, yielding residual induction, coercive field strength, knee field, energy product, and recoil permeability; it is applicable to materials with H<sub>ci</sub> between about 100 Oe and 35 kOe (8 kA/m to 2.8 MA/m) and B<sub>r</sub> from 500 G to 20 kG (50 mT to 2 T). High-coercivity rare-earth specimens may need magnetizing fields beyond what iron-core electromagnets produce, so they are premagnetized externally before transfer into the measuring yoke.<sup>[8](https://store.astm.org/a0977_a0977m-07.html)</sup> For open-circuit measurement, IEC 60404-7 specifies a method applicable to all magnetic materials with coercivities from 0.2 A/m to 160 kA/m, with special precautions below 40 A/m, in highly conductive materials, and for non-ellipsoidal specimens.<sup>[7](https://www.evs.ee/en/evs-en-iec-60404-7-2020)</sup>

## References

1. [NPTEL, Physics of Magnetic Recording, Lecture 35: Coercivity](https://archive.nptel.ac.in/content/storage2/courses/115103038/pdf/mod5.pdf)
2. [Coercive force, IEEE Technology Navigator](https://technav.ieee.org/topic/coercive-force/)
3. [Magnetism in Matter, University Physics Volume 2, OpenStax](https://openstax.org/books/university-physics-volume-2/pages/12-7-magnetism-in-matter)
4. [Magnetic Material, ScienceDirect Topics](https://www.sciencedirect.com/topics/chemistry/magnetic-material)
5. [Coercivity, ScienceDirect Topics](https://www.sciencedirect.com/topics/engineering/coercivity)
6. [Most frequently asked questions about the coercivity of Nd-Fe-B permanent magnets, PMC](https://pmc.ncbi.nlm.nih.gov/articles/PMC8183520/)
7. [EVS-EN IEC 60404-7:2020, Method of measurement of the coercivity of magnetic materials in an open magnetic circuit](https://www.evs.ee/en/evs-en-iec-60404-7-2020)
8. [ASTM A977/A977M-07, Standard Test Method for Magnetic Properties of High-Coercivity Permanent Magnet Materials Using Hysteresigraphs](https://store.astm.org/a0977_a0977m-07.html)
9. [The Feynman Lectures on Physics, Vol. II Ch. 37: Magnetic Materials](https://www.feynmanlectures.caltech.edu/II_37.html)
10. [Cullity & Graham, Introduction to Magnetic Materials, Ch. 1: Definitions and Units](https://www2.fisica.unlp.edu.ar/magnet/Cullity_Graham.pdf)
11. [Soft magnetic materials, IEEE Technology Navigator](https://technav.ieee.org/topic/soft-magnetic-materials/)
12. [istanbul technical university graduate school of science](https://files.core.ac.uk/download/pdf/62733797.pdf)
13. [Perspectives for high-performance permanent magnets: applications, coercivity, and new materials, AIP Advances](https://doi.org/10.1088/2043-6254/aa597c)

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*Topic: Encyclopedia › Physical world and mathematics › Physics › Matter and radiation physics › Condensed matter physics › Electronic and magnetic properties › Magnetism in condensed matter › Domains, magnetization reversal, and micromagnetics*

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