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Zeolites and porous framework materials

7 articles

Extra-large-pore zeolite

An extra-large-pore zeolite is a crystalline microporous framework with pore windows of more than 12 tetrahedral atoms and apertures above 7.5 Å, sought for converting bulky molecules.

ITQ-43

ITQ-43 is a germanosilicate zeolite first synthesized in 2011 in Valencia, Spain, featuring a three-dimensional pore system of 28-ring mesopores and 12-ring micropores, and the first zeolite structure solved ab initio by 3D electron diffraction.

Mayenite electride

Mayenite electride (C12A7:e⁻) is an inorganic electride in which electrons trapped in mayenite's crystal cages act as anions; it is best known as the electron-donating support for ruthenium ammonia synthesis catalysts.

Mechanically interlocked crystals

Mechanically interlocked crystals are crystalline materials whose integrity comes from mechanical bonds, topological entanglements that cannot be separated without breaking a covalent bond, including 2025's 2D interlocked polymers.

RTH zeolite

RTH is a zeolite framework type code in the International Zeolite Association database, describing a two-dimensional small-pore framework whose reference material is RUB-13 and whose 8-ring windows make it relevant to methanol-to-olefins catalysis.

SSZ-13

SSZ-13 is a synthetic small-pore zeolite first made in 1985, best known as the support for Cu-SSZ-13, the catalyst used to cut nitrogen oxides from diesel exhaust.

Zeolite-encapsulated metal clusters

Zeolite-encapsulated metal clusters are subnanometric metal particles, typically below 1 nm, held inside zeolite pores or cages, which protects them from sintering and enables shape-selective catalysis.