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Sodium-ion cathode materials

12 articles

Iron hexacyanoferrate cathode

An iron hexacyanoferrate (FeHCF) cathode is a Prussian blue analog electrode material for sodium-ion and potassium-ion batteries, storing sodium through the Fe2+/Fe3+ couple in an open cubic framework.

Na3V2(PO4)3

Na3V2(PO4)3, commonly abbreviated NVP, is a sodium vanadium phosphate with the NASICON crystal structure serving as a sodium-ion battery cathode with a voltage near 3.4 V.

P2-type layered oxide

A P2-type layered oxide, formula NaxTMO2, is a cathode material for sodium-ion batteries with trigonal-prismatic sodium sites between TMO2 layers, giving fast Na+ diffusion but a poorly reversible P2–O2 transition at high voltage.

Polyanionic sodium-ion cathode

A polyanionic sodium-ion cathode is a sodium-ion battery positive electrode built from tetrahedral anion units like phosphate or sulfate, one of three main cathode families.

Prussian blue analogue cathode

A Prussian blue analog cathode is a positive electrode for rechargeable batteries, mainly sodium-ion cells, built on the open cyanide-bridged framework of Prussian blue and made cheaply by aqueous synthesis.

Prussian white

Prussian white (Na₂Fe[Fe(CN)₆]) is a sodium iron hexacyanoferrate cathode material for sodium-ion batteries, commercialized by CATL in 2021 at 160 Wh/kg and prized for fast sodium-ion transport and cobalt-free chemistry.

Sodium iron phosphate

Sodium iron phosphate, NaFePO₄, is a cathode material for sodium-ion batteries with olivine and maricite phases; the related pyrophosphate NFPP entered 10,000-ton production in 2025.

Sodium layered oxide

A sodium layered oxide is a cathode material for sodium-ion batteries, formula NaxTMO2, with sodium ions between TMO6 slabs and O3, P3, P2, and O2 structural types.

Sodium manganese oxide

Sodium manganese oxide, written NaxMnO2, is a family of compounds serving as cathode materials in sodium-ion batteries, valued because sodium and manganese are abundant and inexpensive.

Sodium nickel manganese oxide

Sodium nickel manganese oxide, abbreviated NNMO and chiefly the composition NaNi0.5Mn0.5O2, is a layered oxide cathode material for sodium-ion batteries, first used in a full cell in 2011.

Sodium vanadium fluorophosphate

Sodium vanadium fluorophosphate (Na₃V₂(PO₄)₂F₃, commonly abbreviated NVPF) is a polyanionic cathode material for sodium-ion batteries, first synthesized in 1999 and used in TIAMAT's commercial cells.

Sodium vanadium phosphate

Sodium vanadium phosphate, abbreviated NVP, is a NASICON-family compound used as a cathode material in sodium-ion batteries, with a 3.4 V operating voltage and 117.6 mAh/g theoretical capacity.