edgepedia

All articles starting with E

17,681 articles

Excited-state iminium and enamine catalysis

Excited-state iminium and enamine catalysis is a branch of asymmetric organocatalysis in which visible light promotes chiral iminium or enamine intermediates to excited states, unlocking radical reactions.

Excited-state transition-metal catalysis

Excited-state transition-metal catalysis is homogeneous catalysis in which a transition metal complex absorbs light and the excited state itself drives bond-making and bond-breaking, without a separate photosensitizer.

Exciter

Exciter is a Canadian speed metal band from Ottawa, Ontario, formed in 1978, whose 1983 debut Heavy Metal Maniac is counted among the first thrash metal albums.

Exciton

An exciton is a bound electron–hole pair that acts as a chargeless quasiparticle in semiconductors and insulators, formed when light excites an electron across the bandgap.

Exciton Bose–Einstein condensation

Exciton Bose–Einstein condensation is the formation of a Bose–Einstein condensate from excitons, bound electron–hole pairs in photoexcited semiconductors. Proposed in 1962, it was directly observed in bulk copper oxide in 2022.

Exciton condensate

An exciton condensate is a Bose–Einstein condensate of excitons, charge-neutral electron–hole pairs bound by the Coulomb interaction, known for dissipationless energy transport and quantum Hall drag, first observed in semiconductor double quantum wells.

Exciton condensation

Exciton condensation is the formation of a coherent quantum state in which many bound electron-hole pairs, called excitons, occupy a single ground state like Bose-Einstein condensation.

Exciton condensation in electron-hole bilayers

Exciton condensation in electron-hole bilayers is a quantum state in which electrons bound to holes in a neighboring layer condense into a coherent superfluid-like ground state.

Exciton diffusion

Exciton diffusion is the random-walk spreading of bound electron–hole pairs through a semiconductor after light excitation, governing energy transport in 2D materials and organic semiconductors.

Exciton diffusion length

The exciton diffusion length is the average distance an exciton travels in a semiconductor before recombining, a key design parameter for organic solar cells and LEDs.

Exciton funneling

Exciton funneling is the directed transport of excitons, neutral electron-hole pairs, toward regions of lower energy created by strain gradients in atomically thin semiconductors like monolayer WSe₂.

Exciton funneling in van der Waals heterostructures

Exciton funneling in van der Waals heterostructures is the directed transport of excitons through stacks of atomically thin materials, driven by strain, electric fields, or dielectric patterning.

Exciton Mott transition

The exciton Mott transition is the density-driven ionization of bound excitons into a conducting electron-hole plasma, reached in 2D semiconductors like MoS2 and WSe2 at critical densities around 10^12 to 10^13 cm^-2.

Exciton polariton

An exciton polariton is a quasiparticle formed by strong coupling between an exciton and a photon, usually a photon confined in an optical microcavity, enabling polariton lasers and quantum fluids of light.

Exciton superfluidity

Exciton superfluidity is a quantum state of matter in which excitons, bound electron–hole pairs, condense and flow without viscosity, now studied mainly in van der Waals heterostructures.

Exciton transport

Exciton transport is the propagation of bound electron–hole pairs in semiconductors from where light generates them to where they recombine, underpinning solar cells and LEDs.

Exciton-polariton topological insulator

An exciton-polariton topological insulator is a photonic device in which polaritons in a honeycomb lattice of microcavities carry edge states that flow one way around defects, first demonstrated in 2018.

Exciton-polaron

An exciton-polaron is a quasiparticle in which an exciton, a bound electron-hole pair, is dressed by a Fermi sea of carriers or by lattice distortions in two-dimensional materials.

Exciton–magnon coupling

Exciton–magnon coupling is the interaction between an exciton and a magnon in a magnetic semiconductor, allowing optical excitations to read and manipulate spin information, most prominently in CrSBr.

Exciton–polariton condensation in perovskite nanowire cavities

Exciton–polariton condensation in perovskite nanowire cavities is the room-temperature formation of a coherent, laser-like state in which exciton–polariton quasiparticles condense in a perovskite nanowire that is both gain medium and cavity.

Excitonic insulator

An excitonic insulator is a state of matter in which bound electron–hole pairs, called excitons, form spontaneously and condense, first proposed by Nevill Mott in the early 1960s.

Exciva

Exciva GmbH is a privately held Heidelberg-based biopharmaceutical company founded in 2016 by Anton Bespalov, Hans Moebius, and Rao Vepachedu, developing Deraphan, a fixed combination drug for agitation in Alzheimer's disease dementia.

Exclamation mark

Exclamation mark (!), or exclamation point (US), the end punctuation expressing strong emotion, commands, or surprise; also called bang, shriek, screamer; dating to c. 1400 Italy from Latin io!, avoided in formal writing but common in texting.

Exclusion Crisis

Exclusion Crisis (1679–81): English political crisis over barring the Catholic James, Duke of York, from succeeding Charles II. Triggered by the Popish Plot; produced the Whig and Tory parties; defeated by Charles's dissolutions.

Exclusion limits in dark-matter searches

An exclusion limit in dark-matter searches is an upper bound, quoted at a stated confidence level, on a dark-matter particle's scattering cross-section as a function of its mass.

Exclusion of anarchists from the Second International

Exclusion of anarchists from the Second International: via admission rules at Brussels 1891, Zurich 1893, and London 1896, anti-parliamentary anarchists were barred from congresses and definitively suspended from membership.

Exclusion of the Portuguese

The Exclusion of the Portuguese was a 1639 edict by which the Tokugawa shogunate banned Portuguese ships from Japan, leaving trade with Europeans to the Dutch, confined to Dejima from 1641.

Exclusion process

An exclusion process is a stochastic interacting particle system where particles hop in continuous time on discrete sites, at most one per site; its asymmetric form, the ASEP, is a paradigm of non-equilibrium statistical physics.

Exclusionary rule

The exclusionary rule is a US judge-made doctrine barring government use of evidence obtained in constitutional violation, established federally in Weeks v. United States (1914) and extended to states by Mapp v. Ohio (1961), with exceptions such as good faith and inevitable discovery.

Exclusive (album)

Exclusive is Chris Brown's second studio album, released November 6, 2007 on CBE and Jive Records; 18 R&B tracks including Kiss Kiss and With You, reissued June 2008 as The Forever Edition adding Forever.